涉“氢”反应动力学

1. Z. Hao#, S. Dong#, Y. Lin* and H. Zhang*, Probe the Formation of Palladium Carbide and Palladium Hydride over Pd-Cu Bimettallic Catalyst and Consequential Regulation of Selective Hydrogenation, XXXX., 2025, in preparation

2. J. Guo, H. Zhang*, Overlayer Stacking Promotes the Hydrogen Spillover, Nano Lett., 2025, 25, 14723-14729 (invited and was dedicated to the 10th anniversary of MSE@NKU)

3. J. Guo#, L. Che#, Y. Qin#, Y. Hu, X. Tai, J. Yuan, L. Jin*, Y. Lin* and H. Zhang*, Atomic-level Electronic Modification: Design and Preparation of Bimetallic Catalysts via Atomic Layer Deposition for Methanol Steam Reforming, Angew. Chem. Int. Ed.,2025, e202514431

4. Y. Yan#, J. Yuan# and H. Zhang*, Constructing Co2@C3N4 Dual-Atomic Site for Highly Efficient Electrochemical H2O2 Production, J. Catal., 2025, under review

5. K. Lu, H. Zhang*, Study on the Mechanism of Ethanol Dry Reforming via Thermodynamic and Kinetic Investigations: Clarifying the Contribution of Tandem and Parallel Reactions in Syngas Production, ACS Catal., 2025, 15, 10092-10108

6. Y. Hu#, R. Liu#, D. Wu, P. Gao, G. Hou, H. Zhang*, W. Dai*, Evidence of Water Promotes Cyclohexanol Adsorption and Dehydration over H-ZSM-5 Zeolite, Nat. Commun., 2025, 16, 5851

7. X. Wang, H. Zhang*, The Nature of Interfacial Catalysis over Pt/NiAl2O4: Effects of Metal Identity and CO Tolerance in Hydrogen Production from Methanol Reforming Reaction,  J. Catal., 2024, 443, 115923

8. J. Guo, H. Zhang*, Escaping from Sabatier Principle by Introducing a Confined Environment: A Case Study on Phenylacetylene Semi-hydrogenation over Nickel-based Catalysts, J. Catal., 2024, 433, 115465

9. Z. He, H. Zhang*, Converting CO2 Into Natural Gas Within the Autoclave: A Kinetic Study on Hydrogenation of Carbonates in Aqueous Solution, ChemSusChem, 2024, e202400478

10. X. Wang#, D. Li#, Z. Gao#, Y. Guo*, H. Zhang*, D. Ma*, The Nature of Interfacial Catalysis over Pt/NiAl2O4 for Hydrogen Production from Methanol Reforming Reaction, J. Am. Chem. Soc., 2023, 145, 905-918

11. J. Yuan#, Z. He#, H. Zhang*, Evidence of C–H Bond Activation Dominating in both C6H12 Oxidation and Consequential C–C Bond Rupture, J. Catal., 2023, 423, 34-49

12. Z. He, Q. Lei, W. Dai, H. Zhang*, Solvent Tunes the Selectivity of Alkenes Epoxidation over Ti-Beta Zeolite: A Systematic Kinetic Assessment on Elementary Steps, Kinetically Relevant and Reaction Barriers, J. Catal., 2023, 421, 172-184

13. L. Che, J. Guo, Z. He, H. Zhang*, Evidence of Rate-determining Step Variation along Reactivity in Acetylene Hydrogenation: a Systematic Kinetic Study on Elementary Steps, Kinetically Relevant (s) and Active Species,  J. Catal., 2023, 414, 336-348

14. J. Guo, M. Peng, Z. Jia, C. Li, H. Liu, H. Zhang*, D. Ma*, Kinetic Evidence of Most Abundant Surface Intermediates Variation over Ptn and Ptp: Few-Atom Pt Ensembles Enable Efficient Catalytic Cyclohexane Dehydrogenation for Hydrogen Production-II, ACS Catal., 2022, 12, 7248-7261

15. J. Dai, H. Zhang*, Evidence of Undissociated CO2 Involved in the Process of CH Bond Activation in Dry Reforming of CH4, J. Catal., 2022, 410, 266-279

16. X. Wang, H. Zhang*, Kinetically Relevant Variation Triggered by Hydrogen Pressure: A Mechanistic Case Study of CO2 Hydrogenation to Methanol over Cu/ZnO, J. Catal., 2022, 406, 145-156

17. Y. Wang, J. Ma, X. Wang, Z. Zhang, J. Zhao, J. Yan, Y. Du*, H. Zhang*, D. Ma*, Complete CO Oxidation by O2 and H2O over Pt-CeO2-δ/MgO Following Langmuir-Hinshelwood and Mars-van Krevelen Mechanisms, Respectively, ACS Catal., 2021, 11, 11820-11830

18. J. Guo, Z. Feng, J. Xu, J. Zhu, G. Zhang, Y. Du*, H. Zhang*, C. Yan, Facile Preparation of Methyl Phenols from Ethanol over Lamellar Ce(OH)SO4·xH2O, ACS Catal., 2021, 11, 6162-6174

19. Y. Wang, C. Zhang, X. Wang, J. Guo, Z. Sun*, H. Zhang*, Site-Selective CO2 Reduction over Highly Dispersed Ru-SnOx Sites Derived from a [Ru@Sn9]6– Zintl Cluster, ACS Catal., 2020, 10, 7808-7819

20. H. Zhang, M. YS Ibrahim, D. W Flaherty*, Aldol Condensation among Acetaldehyde and Ethanol Reactants on TiO2: Experimental Evidence for the Kinetically Relevant Nucleophilic Attack of Enolates, J. Catal., 2018, 361, 290-302

21. H. Zhang, C. Canlas, A. J. Kropf, J. W. Elam, J. A. Dumesic, C. L. Marshall*, Enhancing the Stability of Copper Chromite Catalysts for the Selective Hydrogenation of Furfural with ALD Overcoating (II) – Comparison between TiO2 and Al2O3 Overcoatings, J. Catal., 2015, 326, 172-181

22. H. Zhang, Y. Lei, A J. Kropf, G. Zhang, J. W Elam, J. T Miller, F. Sollberger, F. Ribeiro, M C. Akatay, E. A Stach, J. A Dumesic, C. L Marshall*, Enhancing the Stability of Copper Chromite Catalysts for the Selective Hydrogenation of Furfural Using ALD Overcoating, J. Catal., 2014, 317, 284-292

23. H. Zhang, X. Gu, C. Canlas, A J. Kropf, P. Aich, J. P Greeley, J. W Elam, R. J Meyers, J. A Dumesic, P. C Stair, C. L Marshall*, Atomic Layer Deposition overcoating: Tuning Catalyst Selectivity for Biomass Conversion, Angew. Chem. Int. Ed., 2014, 53(45): 12132-12136

24. H. Zhang,  X. Pan*, X. Han, X. Liu, X. Wang, W. Shen, X. Bao*, Enhancing Chemical Reactions in a Confined Hydrophobic Environment: An NMR Study of Benzene Hydroxylation in Carbon Nanotubes, Chem. Sci., 2013, 4: 1075-1078

25. H. Zhang, X. Pan*, J. Liu, W. Qian, F. Wei, Y. Huang, X. Bao*, Enhanced Catalytic Activity of Sub‐nanometer Titania Clusters Confined inside Double‐Wall Carbon Nanotubes, ChemSusChem, 2011, 4(7), 975-980

入选天津市人才项目（2018），南开大学“百名青年学科带头人”培养计划（2018）

• 张洪波，博士，特聘研究员，博士生导师。南开大学本科（2006），2012年博士毕业于中国科学院大连化学物理研究所，师从包信和院士、潘秀莲研究员。先后在美国国家实验室（Argonne）、宾州州立大学和伊利诺伊大学香槟分校等地进行博士后研究工作（2013~2017）。2018年入职南开大学材料科学与工程学院，受聘特聘研究员。长期从事催化反应机理性研究，擅长借助原子层沉积技术构建、优化催化反应模型体系，研究聚焦于加氢、脱氢、重整等催化反应过程。近年来，以通讯/第一作者在J. Am. Chem. Soc., Angew. Chem. Int. Ed.（2篇）, Nat. Commun., ACS Catal.（5篇）, J. Catal. （10篇）等化学/催化类学术期刊上发表学术论文50余篇。

  
  

  课题组网站：http://nankai.teacher.360eol.com/teacherBasic/preview?teacherId=5992

  
  

• 主持   南开大学“百名青年学科带头人”培养计划启动经费 （2018-2024；023-63186008）200万
  

主持   面上基金项目：限域空间内的Sabatier原理--基于原子层沉积技术的炔烃选择性加氢反应性能调控及相关机理研究 （2025-2028；22572090）50万

主持   面上基金项目：原子层沉积技术构建新型限域Lewis酸催化体系实现乙醇定向转化机理研究 （2022-2025；22172078）60万

主持   中石化委托项目：正构烷烃催化裂解机理研究及性能调控 （2024年度） 48 万

参与   联合基金项目：甲醇直接氧化制聚甲氧基二甲醚反应机理研究及高效催化剂创制（2026-2029；U25A20554）60万/258万

参与   海河实验室（天津市），“131”团队（天津市），渤海沧州研究院重点项目等