Transferred Polymer-Encapsulated Metal Electrodes for Electrical Transport Measurements on Ultrathin Air-Sensitive Crystals

Author:Date:2023-11-21Views:11

论文题目:Transferred Polymer-Encapsulated Metal Electrodes for Electrical Transport Measurements on Ultrathin Air-Sensitive Crystals

论文作者:Zheshan Zhang, Xinyue Dong, Jiabiao Chen, Zhaochao Liu, Zhansheng Gao, Xinyue Chang, Yaping Du*, Chuancheng Jia, Huixia Fu*, Feng Luo*, Jinxiong Wu*

发表期刊:Small Methods2023,  7, 2300177.

Abstract

Owing to rapid property degradation after ambient  exposure and incompatibility with conventional device fabrication  process, electrical transport measurements on air-sensitive 2D materials  have always been a big issue. Here, for the first time, a facile  one-step polymer-encapsulated electrode transfer (PEET) method  applicable for fragile 2D materials is developed, which showed great  advantages of damage-free electrodes patterning and in situ polymer  encapsulation preventing from H2O/O2 exposure during the whole electrical measurements process. The ultrathin SmTe2  metals grown by chemical vapor deposition (CVD) are chosen as the  prototypical air-sensitive 2D crystals for their poor air-stability,  which will become highly insulating when fabricated by conventional  lithographic techniques. Nevertheless, the intrinsic electrical  properties of CVD-grown SmTe2 nanosheets can be readily  investigated by the PEET method instead, showing ultralow contact  resistance and high signal/noise ratio. The PEET method can be  applicable to other fragile ultrathin magnetic materials, such as  (Mn,Cr)Te, to investigate their intrinsic electrical/magnetic  properties.