课题组以配位化学和材料化学为主要研究手段，具体研究方向包括以下几个方面：

1. 负价全金属团簇 

2. 金属-金属键作用

3. 稀土新能源材料

1997-2001    武汉大学                                                学士

2001-2006    中科院福建物构所                             博士

2006-2008    美国太平洋西北国家实验室         博士后

2008-2010    美国北达科他州立大学                   博士后

2010-2018    中科院长春应化所                             研究员

2018-               南开大学                                                教授

获奖及荣誉

国家基金委优青

中科院长春分院青年先锋

天津市领军人才

诚挚欢迎有机合成化学、金属有机化学和理论化学等研究背景的同学加入我们；长期招聘博士后，有意者请直接联系孙老师！

团队理念：做有品位的科研，做原创性的发现；独立之精神，自由之思想。

专著章节：

1. Lei Qiao, John E. McGrady, Zhong-Ming Sun

"Zintl Chemistry: From Zintl ions to Zintl clusters"

Comprehensive Inorganic Chemistry III, Chapter 14 (18500 words), 2021, 下载.pdf

2. M. Kulichenko, N. Fedik, Nikolay V. Tkachenkoa, Á. Muñoz-Castro, Zhong-Ming Sun, A. I. Boldyrev 

“Spherical aromaticity in inorganic chemistry“

Aromaticity, 2021, Chapter 14, 447-488 下载Aromaticity.pdf

3. Nikolay V. Tkachenko, Zhong-Ming Sun, A. I. Boldyrev, A. Muñoz-Castro

"Advances in Cluster Bonding. Bridging Superatomic Building Blocks via Intercluster Bonds"

Atomic Clusters with Unusual Structure, Bonding and Reactivity, 2022, Chapter X

部分论文:

1. Wei-Qiang Zhang, Harry W. T. Morgan, John E. McGrady*, Zhong-Ming Sun*

Synthesis and characterisation of the ternary intermetalloid clusters {M@[As8(ZnMes)4]}3– (M = Nb, Ta) from binary [M@As8]3– precursors

Chem. Sci., 2022, doi.org/10.1039/D2SC01748B

2. Harry W. T. Morgan, Cong-Cong Shu, Zhong-Ming Sun*, John E. McGrady*

A missing link in the growth of lead-based Zintl clusters: isolation of the dimeric plumbaspherene [Cu4Pb22]4–

J. Am. Chem. Soc. 2022, 144, 8007-8017

3. Zi-Chuan Wang, Lei Qiao, Zhong-Ming Sun*, Manfred Scheer

Inorganic Ferrocene Analogue [Fe(P4)2]2-

J. Am. Chem. Soc. 2022, 144, 6698-6702  (JACS spotlight, ACS Editors' Choice, highlighted by Chemistry World,ChemistryViews)

4. Hong-Lei Xu, N. V. Tkachenko, D. W. Szczepanik, I. A. Popov, A. Muñoz-Castro, A. I. Boldyrev,* Zhong-Ming Sun*

Symmetry Collapse due to the Presence of Multiple Local Aromaticity in [Ge24]4- 

Nature Commun. 2022, 13, 2149 (Feature Article)

5. Yu-He Xu, N. V. Tkachenko, Ivan A. Popov, Lei Qiao, A. Muñoz-Castro, A. I. Boldyrev, Zhong-Ming Sun*

Ternary Aromatic and Anti-aromatic Clusters Derived from the Hypho Species [Sn2Sb5]3- 下载.pdf

Nature Commun. 2021, 12, 4465

6. Yi Wang, John E. McGrady, Zhong-Ming Sun*

Solution-Based Group 14 Zintl Anions: New Frontiers and Discoveries下载.pdf

Acc. Chem. Res. 2021, 54, 1506-1516

7. Hong-Lei Xu, Nikolay V. Tkachenko, Alvaro Muñoz-Castro,  Alexander I. Boldyrev*, Zhong-Ming Sun*
 [Sn8]6--bridged mixed-valence Zn(I)/Zn(II) in {[K2ZnSn8(ZnMes)]2}4- Inverse Sandwich-Type Cluster Supported by Zn(I)-Zn(I) Bond anie.下载.pdf
Angew. Chem. Int. Ed. 2021, 60(18), 9990-9995

8. Hong-Lei Xu, Nikolay V. Tkachenko, Zi-Chuan Wang, Wei-Xing Chen,  Lei Qiao, Alvaro Muñoz-Castro, A.I. Boldyrev*, Zhong-Ming Sun* 

"A Sandwich-Type Cluster Containing Ge@Pd3 Planar Fragment Flanked by Aromatic Nonagermanide Caps" 下载pdf

Nature Commun. 2020, 11, 5286 (Feature Article)

9. Lei Qiao, Chao Zhang, Cong-Cong Shu, Harry Morgan, John E. McGrady,*  Zhong-Ming Sun* 

“[Cu4@E18]4– (E=Sn, Pb): Fused Derivatives of Endohedral Stannaspherene and Plumbaspherene“ 下载pdf

J. Am. Chem. Soc. 2020, 142(31), 13288–13293

10. Hong-Lei Xu, I. A. Popov, N. V. Tkachenko, Zi-Chuan Wang, A. Muñoz-Castro, A.I. Boldyrev,* Zhong-Ming Sun,*  

sigma-Aromaticity-Induced Stabilization of Heterometallic Supertetrahedral Clusters [Zn6Ge16]4- and [Cd6Ge16]4-下载pdf

Angew. Chem. Int. Ed. 2020, 59 (39), 17286 (Hot Paper)

11. Cong-Cong Shu, H. W. T. Morgan, L. Qiao, J. E.McGrady*, Zhong-Ming Sun*  

“A family of lead clusters with precious metal cores” 下载pdf

Nature Commun. 2020, 11, 3477  (Feature Article)

12.  Chao Liu, N. V. Tkachenko, I. A. Popov, N. Fedik, Xue Min, C.-Q. Xu,Jun Li, J. E. McGrady, A. I. Boldyrev, Zhong-Ming Sun*

Structure and Bonding in [Sb@In8Sb12]3- and [Sb@In8Sb12]5–下载pdf

Angew. Chem. Int. Ed. 2019, 58(25), 8367-8371  (Inside Cover)

13. Chao Liu, Xiao Jin, Lei-Jiao Li, Jun Xu, John E. McGrady*  Zhong-Ming Sun*

Synthesis and structure of a family of rhodium polystannide clusters [Rh@Sn10]3–, [Rh@Sn12]3–, [Rh2@Sn17]6– and the first triply-fused stannide, [Rh3@Sn24]5–

Chem. Sci., 2019,10, 4394-4401 (Cover)

14. Xue Min, Ivan A. Popov, Fu-Xing Pan, Lei-Jiao Li, Eduard Matito, Zhong-Ming Sun,* Lai-Sheng Wang, Alexander I. Boldyrev*

All-Metal Antiaromaticity in Sb4-Type Lanthanocene Anions下载pdf

Angew. Chem. Int. Ed. 2016, 55(18), 5531-5535 

For a  highlight of this paper, see: Ritter, S. K. “Cyclic antimony complexes take aromaticity to a new level" Chemical & Engineering News, 2016, 94, P5

15.  Ivan A. Popov, Fu-Xing Pan, X.-R. You, Lei-Jiao Li, E. Matito, C. Liu, H.-J. Zhai, Zhong-Ming Sun,*  Alexander I. Boldyrev* 

“Peculiar All-Metal sigma-Aromaticity of the [Au2Sb16]4-  Anion in the Solid”下载pdf

Angew. Chem. Int. Ed. 2016, 55(49), 15344–15346

16. Fu-Xing Pan , Lei-Jiao Li , Ying-Jin Wang , Jin-Chang Guo , Hua-Jin Zhai*, Li Xu, Zhong-Ming Sun* 

“An All-Metal Aromatic Sandwich Complex [Sb3Au3Sb3]3-”下载pdf

J. Am. Chem. Soc. 2015, 137, 10954-10957.  

For a  highlight of this paper, see: Ritter, S. K. “All-Metal Sandwich Is Now On The Menu，Chemical & Engineering News 2015,93 (34) 24.  This article was also featured as a JACS spotlight

17. Jing Zhang, Jun-Feng Liu, Angel Ugrinov, Anthony F. X. Pillai, Zhong-Ming Sun*, Pinjing Zhao* 

Methoxy-Directed Aryl-to-Aryl 1,3-Rhodium Migration

J. Am. Chem. Soc. 2013, 135 (46), 17270–17273

独立开展工作前

18. Zhong-Ming Sun, Jing Zhang, Rajith S. Manan, Pinjing Zhao*  

“Rh(I)-Catalyzed Olefin Hydroarylation with Electron-Deficient Perfluoroarenes”

J. Am. Chem. Soc. 2010,132, 6935-6937.

19. Zhong-Ming Sun, Pinjing Zhao*  

“Rhodium-Mediated Decarboxylative Conjugate Addition of Fluorinated Benzoic Acids: Stoichiometric and Catalytic Transformations”

Angew. Chem. Int. Ed. 2009, 48, 6854-6858.

20. Zhong-Ming Sun,Hai Xiao, Jun Li, Lai-Sheng Wang*

“[Pd2@Sn18]4-: Fusion of two endohedral stannaspherenes”

J. Am. Chem. Soc. 2007, 129, 9560-9561.