新型多孔材料（MOFs,COFs,POCs, HOFs）的设计合成及功能化；光电功能材料设计与开发；功能多孔催化剂创制；吸附分离粉体及膜材料构筑。

李柏延，南开大学材料科学与工程学院特聘研究员、博士生导师、国家海外青年高层次人才获得者、南开大学“百名青年学科带头人”。2012年毕业于吉林大学，导师施展教授。曾先后在美国南佛罗里达大学马胜前教授课题组、美国罗格斯大学李静教授课题组和沙特国王科技大学韩宇教授课题组从事博士后研究工作。2019年加入南开大学工作至今。近年来，主要围绕多孔晶体材料（包括COFs、MOFs和POCs）的宏量制备方法开发、任务导向的功能多孔材料定向构筑及在能源化学、环境化工、绿色化工领域应用开展系列工作。以第一作者、通讯作者在Nature Communications （4）, J. Am. Chem. Soc（6）., Angew. Chem. Int. Ed.（3）, Coordin. Chem. Rev.等学术期刊发表论文60余篇，被引用5000余次，多篇文章入选ESI高被引论文。担任海外高层次人才计划项目、面上基金项目、国家重点研发计划课题负责人等，获授权中国、美国发明专利5项，获吉林省自然科学学术成果一等奖一项（第二完成人）。应邀担任《Chinese Chemical Letters》《应用化学》杂志的青年编委。

代表论文

(1) Laiyu Zhang, Qiong Lei, Mao Yi, Zhiyuan Zhang, Xin Lian, Jian Xu, Shuo Zhang*, Lin Li*,Baiyan Li*,Xian-He Bu, Bioinspired “Intermolecular Pocket” in Soft Molecular Crystal of Porous Organic CageExhibiting Reversible Guest Recognition, Angew. Chem. Int. Ed, 2024, accepted.

(2) Zhiyuan Zhang, Shuo Zhang, Xiongli Liu, Lin Li, Shan Wang, Rufeng Yang, Laiyu Zhang, Zifeng You, Feng Shui, Shiqi Yang, Zhendong Yang, Qiao Zhao, Baiyan Li^* Xian-He Bu Efficient Fluorocarbons Capture Using Radical-Containing Covalent Triazine Frameworks, J. Am. Chem. Soc. 2024, accepted.

(3) Xiongli Liu, Zhiyuan Zhang, Feng Shui,Shuo Zhang, Lin Li, Junhua Wang, Mao Yi, Zifeng You,Shiqi Yang, Rufeng Yang, Shan Wang, Yilian Liu, Qiao Zhao, Baiyan Li*, Xian-He Bu*, Shengqian Ma* Porous Organic Cage as an Effecient Platform for Industrial Radioactive Iodine Capture, Angew. Chem. Int. Ed, 10.1002/anie.202411342

(4) Xiongli Liu , An Wang, Chunping Wang , Jinli Li, Zhiyuan Zhang,Abdullah M. Al-Enizi , Ayman Nafady, Feng Shui,  Zifeng You, Baiyan Li*,Yangbing Wen*& Shengqian Ma*. A general large-scale synthesis approach for crystalline porous materials, Nat. Commun. 2023, 14, 7022.

(5) Xue-Nan Feng, Yi Yang, Xuejie Cao, Ting Wang, De-Ming Kong, Xue-Bo Yin,* Baiyan Li,* Xian-He Bu. General Approach to Construct C−C Single Bond-Linked Covalent Organic Frameworks, J. Am. Chem. Soc. 2023, 145, 21284−21292.

(6) Zhiyuan Zhang, Xinglong Dong, Jun Yin, Zhi-Gang Li, Xue Li, Daliang Zhang, Tingting Pan, Qiong Lei, Xiongli Liu, Yaqiang Xie, Feng Shui, Jinli Li, Mao Yi, Jin Yuan, Zifeng You, Laiyu Zhang, Jianhong Chang, Hongbo Zhang, Wei Li, Qianrong Fang, Baiyan Li*, Xian-He Bu,* and Yu Han*, Chemically Stable Guanidinium Covalent Organic Framework for the Efficient Capture of Low-Concentration Iodine at High Temperatures, J. Am. Chem. Soc. 2022, 144, 6821-6829.

(7) Xiongli Liu, Changjia Zhu, Jun Yin, Jixin Li, Zhiyuan Zhang, Jinli Li, Feng Shui, Zifeng You, Zhan Shi, Baiyan Li*, Xian-He Bu*, Ayman Nafady, Shengqian Ma*, Installation of synergistic binding sites onto porous organic polymers for efficient removal of perfluorooctanoic acid, Nat. Commun, 2022, 13, 2132.

(8) Baiyan Li, Xinglong Dong, Hao Wang, Dingxuan Ma, Kui Tan, Stephanie Jensen, Benjamin J. Deibert, Joseph Butler, Jeremy Cure, Zhan Shi, Timo Thonhauser, Yves J. Chabal, Yu Han & Jing Li*, Capture of organic iodides from nuclear waste by metal-organic framework-based molecular traps, Nat. Commun., 2017, 8, 485.

(9) Baiyan Li, Yiming Zhang, Dingxuan Ma, Zhan Shi, Shengqian Ma*, Mercury nano-trap for highly effective and highly efficient removal of mercury(II) from aqueous solution, Nat. Commun. 2014, 5, 5537.

(10) Baiyan Li, Kunyue Leng, Yiming Zhang, James J. Dynes, Jian Wang, Yongfeng Hu, Dingxuan Ma, Zhan Shi, Liangkui Zhu, Daliang Zhang, Yinyong Sun*, Matthew Chrzanowski, and Shengqian Ma*, Metal−Organic Framework Based upon the Synergy of a Brønsted Acid Framework and Lewis Acid Centers as a Highly Efficient Heterogeneous Catalyst for Fixed-Bed Reactions. J. Am. Chem. Soc. 2015, 137, 4243.

(11) Baiyan Li, Yiming Zhang, Rajamani Krishna, Kexin Yao, Yu Han, Zili Wu, Dingxuan Ma, Zhan Shi, Tony Pham, Brian Space, Jian Liu, Praveen K. Thallapally, Jun Liu, Matthew Chrzanowski, and Shengqian Ma*, Introduction of π‑Complexation into Porous Aromatic Framework for Highly Selective Adsorption of Ethylene over Ethane, J. Am. Chem. Soc. 2014, 136, 8654.

(12) Baiyan Li, Yiming Zhang, Dingxuan Ma, Tianliang Ma, Zhan Shi, and Shengqian Ma*, Metal-Cation-Directed de Novo Assembly of a Functionalized Guest Molecule in the Nanospace of a Metal−Organic Framework, J. Am. Chem. Soc. 2014, 136, 1202.

(13) Baiyan Li, Zhijuan Zhang, Yi Li, Kexin Yao, Yihan Zhu, Zhiyong Deng, Fen Yang, Xiaojing Zhou, Guanghua Li, Haohan Wu, Nour Nijem, Yves J. Chabal, Zhiping Lai, Yu Han, Zhan Shi*, Shouhua Feng, and Jing Li*, Enhanced binding affinity, remarkable selectivity, and high capacity of CO2 by dual functionalization of a rht-type metal–organic framework, Angew. Chem. Int. Ed., 2012, 1412.

(14) Baiyan Li, Matthew Chrzanowski, Yiming Zhang and Shengqian Ma*, Applications of Metal-Organic Frameworks Featuring multi-Functional Sites, Coord. Chem. Rev. 2016, 307, 106-129.

(15) Baiyan Li, Yiming Zhang, Dingxuan MaZhenyu Xing, Tianliang Ma, Zhan Shi*, Xiulei Ji and Shengqian Ma*, Creation of a New Type of Ion Exchange Materials for Rapid, High-Capacity, Reversible and Selective Ion Exchange without Swelling and Entrainment, Chem. Sci., 2016, 7, 2138-2144.

(16) Baiyan Li, Dingxuan Ma, Yi Li, Yiming Zhang, Guanghua Li, Zhan Shi*, Shouhua Feng, Michael J. Zaworotko*, and Shengqian Ma*, Dual Functionalized Cages in Metal–Organic Frameworks via Stepwise Postsynthetic Modification, Chem. Mater., 2016, 28 (13), 4781.

(17) Junhua Wang, Xin Lian, Xichuan Cao*, Qiao Zhao*, Baiyan Li*, Xian-He Bu*. Dual polarization strategy to enhance CH4 uptake in covalent organic frameworks for coal-bed methane purification. Chinese. Chem. Lett, 2024, 35, 109180.

(18) Feng Shui, Qiong Lei, Xinglong Don, Tingting Pan, Zhiyuan Zhang, Jinli Li, Mao Yi, Laiyu Zhang , Xiongli Liu, Zifeng You, Shiqi Yang, Rufeng Yang, Hongbo Zhang, Jixin Li, Zhan Shi, Jun Yin*, Baiyan Li*, Xian-He Bu*. Iodine nanotrap for highly efficient iodine capture under high temperature, Chem. Eng. J. 2023, 468, 143525.

(19) Junhua Wang, Xin Lian, Zhiyuan Zhang, Xiongli Liu, Qiao Zhao, Jian Xu, Xichuan Cao*, Baiyan Li* and Xian-He Bu*. Thiazole functionalized covalent triazine frameworks for C2H6/C2H4 separation with remarkable ethane uptake. Chem. Commun. 2023, 59, 11240-11243.

(20) Feng Shui, Qiong Lei, Xinglong Dong, Tingting Pan, Zhiyuan Zhang, Jinli Li, Mao Yi, Laiyu Zhang, Xiongli Liu, Zifeng You, Shiqi Yang, Rufeng Ya, Hongbo Zhang, Jixin Li, Zhan Shi, Jun Yin,* Baiyan Li,* Xian-He Bu,* Iodine nanotrap for highly efficient iodine capture under high temperature, Chem. Eng. J. 2023, 468, 143525.

(21) Jinli Li, Qiong Lei, Xinglong Dong, Cailing Chen, Xiongli Liu, Zhiyuan Zhang, Feng Shui, Mao Yi, Baiyan Li,* and Xian-He Bu, Sequential Modification Strategy to Construct Crystalline Benzimidazole Covalent Organic Frameworks with Extraordinary Stability and Polymerization Degree, Chemistry of materials.2023, 35, 4120−4127.

(22) Huaijie Jia, Dingxuan Ma, Shaowei Zhong, Lanjie Li, Lin Li, Lei Xu⁎, Baiyan Li⁎, Boosting Photocatalytic Activity under Visible-light by Creation of PCN-222/g-C3N4 Heterojunctions, Chem. Eng. J. 2019, 368, 165.

(23) Xinyan Zhang, Xinmin Yu, Jixin Li, Lei Xu*, Baiyan Li*,  Construction of MOFs/g-C3N4 Composite for Accelerating Visible-Light-Driven Hydrogen Evolution, Int. J. Hydrogen Energ. 2022, 47, 18007.

(24) Jianan Liu, Qi Li, Xudong Xiao, Fuxiang Li, Chen Zhao, Qi Sun, Panzhe Qiao, Jing Zhou, Jie Wu, Baiyan Li*, Hongliang Bao, Baojiang Jiang*,Metal-Organic Frameworks Loaded on Phosphorus-Doped Tubular Carbon Nitride for Enhanced Photocatalytic Hydrogen Production and Amine Oxidation, J. Colloid. Interf. Sci. 2021, 590, 1.

(25) Baiyan Li, Qi Sun, Yiming Zhang, Carter W. Abney, Briana Aguila, Wenbin Lin, and Shengqian Ma*, Functionalized Porous Aromatic Framework for Efficient Uranium Adsorption from Aqueous Solutions, ACS Appl. Mater. Interfaces 2017, 9, 12511.

(26) Dingxuan Ma, Baiyan Li*,Zhonghua Cui, Kang Liu, Cailing Chen, Guanghua Li, Jia Hua, Benhua Ma, Zhan Shi*, and Shouhua Feng, Multifunctional Luminescent Porous Organic Polymer for Selectively Detecting Iron Ions and 1,4-Dioxane via Luminescent Turn-off and Turn-on Sensing, ACS Appl. Mater. Interfaces 2016, 8, 24097.

(27) Jinli Li, Junhua Wang, Feng Shui, Mao Yi, Zhiyuan Zhang, Xiongli Liu, Laiyu Zhang, Zifeng You, Rufeng Yang, Shiqi Yang, Baiyan Li,* Xian-He Bu, Superhigh intrinsic proton conductivity in densely carboxylic covalent organic framework, Chin. Chem. Lett., 2023, 8, 34,107917.

(28) Dingxuan Ma, Baiyan Li*, Kang Liu, Xianlong Zhang, Weijian Zou, Yongquan Yang, Guanghua Li, Zhan Shi* and Shouhua Feng, Bifunctional MOF Heterogeneous Catalysts Based on The Synergy of Dual Functional Sites for Efficient Conversion of CO2 Under Mild and Co-catalyst Free Conditions, J. Mater. Chem. A 2015, 3, 23136.

(29) Junhua Wang, Xin Lian, Zhiyuan Zhang, Xiongli Liu, Qiao Zhao, Jian Xu, Xichuan Cao,* Baiyan Li,* and Xian-He Bu, Thiazole functionalized covalent triazine frameworks for C2H6/C2H4 separation with remarkable ethane uptake，Chem. Commun, 2023, DOI: 10.1039/d3cc02880a.

(30) Baiyan Li, Youssef Belmabkhout, Yiming Zhang, Prashant M. Bhatt, Hongming He, Daliang Zhang, Yu Han, Mohamed Eddaoudi*, Jason A. Perman and Shengqian Ma*, From an Equilibrium Based MOF Adsorbent to a Kinetic Selective Carbon Molecular Sieve for Paraffin/Iso-Paraffin Separation, Chem. Commun.2016, 52, 13897.

(31) Baiyan Li, Yiming Zhang*, Dingxuan Ma, Liangkui Zhu, Daliang Zhang, Matthew Chrzanowski, Zhan Shi and Shengqian Ma*, Creating Extra Pores in Microporous Carbon via a Template Strategy for a Remarkable Enhancement of Ambient-Pressure CO2 Uptake, Chem. Commun. 2015, 51, 8683.

(32) Baiyan Li, Yiming Zhang, Dingxuan Ma, Lu Li, Guanghua Li, Guo-Dong Li, Zhan Shi* and Shouhua Feng, A Strategy Toward Constructing Bifunctionalized MOF Catalyst: Post-Synthesized Modification of MOFs on Organic Ligands and Coordinatively Unsaturated Metal Sites, Chem. Commun.2012, 48, 6151.

(33) Yiming Zhang, Baiyan Li*, Rajamani Krishna, Zili Wu, Dingxuan Ma, Zhan Shi, Tony Pham, Katherine Forrest, Brian Space and Shengqian Ma*, Highly Selective Adsorption of Ethylene Over Ethane in a MOF Featuring The Combination of Open Metal Site and π-Complexation, Chem. Commun.2015, 51, 2714.

授权发明专利

1、李柏延; 刘雄利; 杨濡峰; 杨世琪.一种应用于高温、低浓度条件下放射性碘吸附的离子型多孔有机笼材料制备方法，ZL202210141108.7，2023年11月03日。

2、李柏延；刘雄利. 一种利用高压均质制备金属有机框架材料的方法，ZL20211074628.2，2022年11月01日。

3、李柏延；张志远.一种高稳定强碱性多孔离子交换材料的制备方法，ZL202110760618.8，2022年05月10日。

4、李柏延；刘雄利. 一种利用高压均质制备共价有机框架材料的方法，ZL202110257296.5，2022年05月06日。

5、Functionalized Porous Organic Polymers for Olefin/Paraffin Separations. Shengqian Ma, Baiyan Li, Patent Number: US9511348B2

主持参与项目

1、多孔有机框架材料增强传统树脂耐热性及力学性能研究，2022年1月-2023年1月，20万，主持

2、可循环放射性单质碘“纳米陷阱”开发（21978138），国家自然科学基金，2020年1月-2023年12月，79.2  万元，主持

3、多孔有机笼构筑“分子陷阱”实现氙气和氪气的高效分离，2024-2027, 50万，主持

4、第15批海外高层次人才，2019年1月-2021年12月，200  万元，主持

5、手性多孔晶态催化材料的定向设计和精准构筑（2022YFA1503301），国家重点研发计划，2022年12月-2027年11月，570万，主持

课题组长期招收博士后、博士生和硕士生，欢迎加盟！