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基于混合分子构筑块策略构筑的具有高化学稳定性的首例杂化三壁MOF材料
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论文题目:The First Example of Hetero-Triple-Walled Metal–Organic Frameworks with High Chemical Stability Constructed via Flexible Integration of Mixed Molecular Building Blocks
论文作者:Dan Tian, Jian Xu, Zhao-Jun Xie, Zhao-Quan Yao, Deng-Lin Fu, Zhen Zhou, Xian-He Bu
发表期刊:Adv Sci, 2016, 3, 1500283   [ pdf ]

An unprecedented 3D hetero-triple-walled metal-organic framework is obtained by straightforward elaboration of the mixed molecular building block (MBB) strategy. In this approach, multiple individual flexible and rigid MBBs are integrated into one composite building block as separate layers, which are of the same shape but different sizes. This MOF shows exceptional water stability and the application of Li-ion battery electrodes.